(4) IB Codes and IP Codes. B82 Cargo tanks and portable tanks are not authorized. 111 Explosive substances of Division 1.1 Compatibility Group A (1.1A) are forbidden for transportation if dry or not desensitized, unless incorporated in a device. c. Primary receptacles may also be further packed in specification bulk outer packagings. Search & Navigation Packagings of other material with a small amount of metal, for example metal closures or other metal fittings such as those mentioned in part 178 of this subchapter, are not considered metal packagings. 135 Internal combustion engines installed in a vehicle must be described using Vehicle, flammable gas powered or Vehicle, flammable liquid powered, as appropriate. In addition, the material also must be covered with an inert gas or the container must be filled with water to the tank's capacity. 385 Notwithstanding the provisions of 177.834(l) of this subchapter, cargo heaters may be used when weather conditions are such that the freezing of a wetted explosive material is likely. The set to discharge for the spring loaded pressure relief device and the burst pressure for the frangible disc, as applicable, must not be greater than 2.65 bar for portable tanks with minimum test pressures greater than 4 bar; b. During transport, it must be protected from direct sunshine and stored (or kept) in a cool and well-ventilated place, away from all sources of heat. A101 In addition to the applicable requirements of 173.185, the quantity of lithium metal in the batteries contained in any piece of equipment must not exceed 12 g per cell and 500 g per battery. In addition, a lighter design intended to contain a non-pressurized Class 3 material is excepted from the examination and testing criteria specified in 173.308(b)(3). B70 If DOT 103ANW tank car tank is used: All cast metal in contact with the lading must have 96.7 percent nickel content; and the lading must be anhydrous and free from any impurities. Packagings of other material constructed with a small amount of metal must be designed such that the hazardous material does not contact the metal. Openings for safety relief devices on multi-unit tank car tanks shall be plugged or blank flanged. Column 8 c. The motor carrier must maintain a satisfactory safety rating as prescribed in 49 CFR part 385. b. 107 The classification of the substance is expected to vary especially with the particle size and packaging but the border lines have not been experimentally determined; appropriate classifications should be verified following the test procedures in 173.57 and 173.58 of this subchapter. A single packaging of a 4C2 sift-proof, natural wood box; or. (c)Column 2: Hazardous materials descriptions and proper shipping names. a. Each tank car must have a reclosing pressure relief device having a start-to-discharge pressure of 10.34 Bar (150 psig). These provisions apply only to transportation by water: W1 This substance in a non friable prill or granule form is not subject to the requirements of this subchapter when tested in accordance with the UN Manual of Test and Criteria (IBR, see 171.7 of this subchapter) and is found to not meet the definition or criteria for inclusion in Division 5.1. (i) Column 8: Packaging authorizations. However this examination is required when the conditions of 180.605(f) are met. The packaging may not be loaded with a material outside of the packaging's design temperature range. The guns are packaged in accordance with Packing Method US 1 as specified in 173.62 of this subchapter. For UN2031 with more than 55% nitric acid, rigid plastic IBCs and composite IBCs with a rigid plastic inner receptacle are authorized for two years from the date of IBC manufacture. The in-page Table of Contents is available only when multiple sections are being viewed. Displaying title 49, up to date as of 3/02/2023. 43 The membrane filters, including paper separators and coating or backing materials, that are present in transport, must not be able to propagate a detonation as tested by one of the tests described in the UN Manual of Tests and Criteria, Part I, Test series 1(a) (IBR, see 171.7 of this subchapter). The temperature of the material at the time it is offered for transport and during transportation may not exceed 55 C (130 F). B65 Tank cars constructed before March 16, 2009, must have a test pressure of 34.47 Bar (500 psig) or greater and conform to Class 105A. Each (6) A code containing the letter R refers to a special provision which applies only to transportation by rail. Lading in unlined tanks must be inhibited so that the corrosive effect on steel is not greater than that of hydrofluoric acid of 65 percent concentration. Each inner packaging contains not more than 30 mL; b. These notes are explained at the end of each TABLE. Regulation Y Column 4 specifies the applicability of 178.275(g)(3) of this subchapter for the pressure relief devices. 132 This description may only be used for ammonium nitrate-based compound fertilizers. 117 If shipment of the explosive substance is to take place at a time that freezing weather is anticipated, the water contained in the explosive substance must be mixed with denatured alcohol so that freezing will not occur. It may not be used to describe articles, machinery, or apparatus for which a proper shipping name exists in the 172.101 Table. 350 Ammonium bromate, ammonium bromate aqueous solutions, and mixtures of a bromate with an ammonium salt are forbidden for transport. If you have questions or comments regarding a published document please You are using an unsupported browser. (5) N codes. IBCs must be packed in closed freight containers or a closed transport vehicle. TP10 A lead lining, not less than 5 mm thick, which shall be tested annually, or another suitable lining material approved by the competent authority, is required. "Published Edition". authorized by name in the Hazardous Materials Table or have been specifically authorized by name either in the Section 172.101 Hazardous Materials Table or have been assigned a shipping name and hazard class by the Associate Administrator for Hazardous Materials Safety. The mixture for suspensions and gels typically has the following composition: 60-85% ammonium nitrate; 0-5% sodium or potassium perchlorate; 0-17% hexamine nitrate or monomethylamine nitrate; 5-30% water; 2-15% fuel; 0.5-4% thickening agent; 0-10% soluble flame suppressants; and trace additives. Orientation markings as described in 172.312(a)(2) are required when liquid hazardous materials may escape due to incorrect orientation. Additionally, self-propelled vehicles or equipment that contain a fuel cell engine must be described using the entries Engine, fuel cell, flammable gas powered or Engine, fuel cell, flammable liquid powered or Vehicle, fuel cell, flammable gas powered or Vehicle, fuel cell, flammable liquid powered, as appropriate. The present arrangement occurs in such a way that one QA molecule is hydrogen-bonded to four neighboring molecules: two different molecules in one column and other two molecules in another column. is the mean coefficient of cubical expansion of the liquid between the mean temperature of the liquid during filling (tf) and the maximum mean bulk temperature during transportation (tr) both in degrees celsius. metal other than steel or aluminum (50N). B120 The use of flexible bulk containers conforming to the requirements in subpart R and subpart S of part 178 of this subchapter is permitted. 176 This entry must be used for formaldehyde solutions containing methanol as a stabilizer. The material must be packaged so that the percentage of diluent does not fall below that stated in the approval at any time during transportation. Table 1. (7) Special Provisions (172.102) IB8, IP2, IP4 134 This entry applies only to vehicles powered by wet batteries, sodium batteries, lithium metal batteries or lithium ion batteries, and equipment powered by wet batteries or sodium batteries that are transported with these batteries installed. The Electronic Code of Federal Regulations (eCFR) is a continuously updated online version of the CFR. A metal hydride storage system installed in or intended to be installed in a vehicle or equipment or in vehicle or equipment components must be approved for transport by the Associate Administrator. Pressure relief devices shall be designed to prevent the entry of foreign matter, the leakage of liquid and the development of any dangerous excess pressure. 41 This material at the Packing Group II hazard criteria level may be transported in Large Packagings. Individual Name: Mr. David Comen. 144 If transported as a residue in an underground storage tank (UST), as defined in 40 CFR 280.12, that has been cleaned and purged or rendered inert according to the American Petroleum Institute (API) Standard 1604 (IBR, see 171.7 of this subchapter), then the tank and this material are not subject to any other requirements of this subchapter. The first label code represents the primary hazard of the material. c. Each glass inner packaging is protected by a means of preventing puncture of the plastic bag (e.g., sleeves or cushioning) in the event of damage to the packaging (e.g., by crushing). (See 173.50 of this subchapter.). switch to drafting.ecfr.gov. N37 This material may be shipped in an integrally-lined fiber drum (1G) which meets the general packaging requirements of subpart B of part 173 of this subchapter, the requirements of part 178 of this subchapter at the packing group assigned for the material and to any other special provisions of column 7 of the 172.101 table. It must not be used for machinery or apparatus for which a proper shipping name already exists in the 172.101 Table. b. (7) A code containing the letter T refers to a special provision which applies only to transportation in UN or IM Specification portable tanks. B131 When transported by highway, rail, or cargo vessel, waste Paint and Paint related material (UN1263; PG II and PG III), when in plastic or metal inner packagings of not more than 26.5 L (7 gallons), are excepted from the marking requirements in 172.301(a) and (c) and the labeling requirements in 172.400(a), when further packed in the following specification and non-specification bulk outer packagings and under the following conditions: a. (a) The Hazardous Materials Table . 79 This entry may not be used for mixtures that meet the definition for oxidizing gas. For liquids transported under ambient conditions may be calculated using the formula: d15 and d50 are the densities (in units of mass per unit volume) of the liquid at 15 C (59 F) and 50 C (122 F), respectively. Equipment powered by lithium metal batteries or lithium ion batteries must be described using the entries Lithium metal batteries contained in equipment or Lithium metal batteries packed with equipment or Lithium ion batteries contained in equipment or Lithium ion batteries packed with equipment, as appropriate. Comments or questions about document content can not be answered by OFR staff. The quantities of hazardous materials do not exceed those specified in 173.4a of this subchapter; and. Others such as copper and silver are available in trace amounts. 163 Substances must satisfactorily pass Test Series 8 of the UN Manual of Tests and Criteria, Part I, Section 18 (IBR, see 171.7 of this subchapter). The caps must not contain more than an average of twenty-five hundredths of a grain of explosive composition per cap; c. The caps must be packed inside packagings constructed of cardboard not less than 0.013-inch in thickness, metal not less than 0.008-inch in thickness, non-combustible plastic not less than 0.015-inch in thickness, or a composite blister package consisting of cardboard not less than 0.013-inch in thickness and non-combustible plastic not less than 0.005-inch in thickness that completely encloses the caps; d. The minimum dimensions of each side and each end of the cardboard packaging must be 1/8th inch in height or more; e. The number of caps inside each packaging must be limited so that not more than 10 grains of explosives composition may be packed into one cubic inch of space, and not more than 17.5 grains of the explosive composition of toy caps may be packed in any inner packaging; f. Inner packagings must be packed in outer packagings meeting PG II performance criteria; g. Toy caps may be packed with non-explosive or non-flammable articles provided the outer packagings are marked as prescribed in this paragraph; h. Toy paper caps of any kind must not be packed in the same packaging with fireworks; i. that, for example, are used for medical, analytical, diagnostic, testing, or repair purposes. B81 Venting and pressure relief devices for tank car tanks and cargo tanks must be approved by the Associate Administrator. A35 This includes any material which is not covered by any of the other classes but which has an anesthetic, narcotic, noxious or other similar properties such that, in the event of spillage or leakage on an aircraft, extreme annoyance or discomfort could be caused to crew members so as to prevent the correct performance of assigned duties. . In addition, MC 312 and DOT 412 cargo tank motor vehicles must: c. Have a MAWP or design pressure of at least 87 psig; and. user convenience only and is not intended to alter agency intent b. b. g. The test results shall be documented, shall be traceable, and shall be made available to a representative of the Department upon request. 420 This entry does not apply to manufactured articles (such as table tennis balls). 106 The recognized name of the particular explosive may be specified in addition to the type. A30 Ammonium permanganate is not authorized for transportation on aircraft. (3) Damage to terminals. This content is from the eCFR and may include recent changes applied to the CFR. Packagings must be sift-proof, prevent liquid water from reaching the hazardous material, and be provided with sufficient venting to preclude dangerous accumulation of flammable, corrosive, or toxic gaseous emissions such as methane, hydrogen, and ammonia. TP6 The tank must be equipped with a pressure release device which prevent a tank from bursting under fire engulfment conditions (the conditions prescribed in CGA pamphlet S-1.2 (see 171.7 of this subchapter) or alternative conditions approved by the Associate Administrator may be used to consider the fire engulfment condition), taking into account the properties of the hazardous material to be transported. and are not subject to requirements of this subchapter except for the following: (a) Incident reporting. 372 This entry applies to asymmetric capacitors with an energy storage capacity greater than 0.3 Wh. The article, machinery, or apparatus, if unpackaged, or the packaging in which it is contained shall be marked Dangerous goods in articles or Dangerous goods in machinery or Dangerous goods in apparatus as appropriate, with the identification number UN3363. Radiation detection systems containing such detectors are not subject to any other requirements of this subchapter provided they are packed in accordance with paragraph c of this special provision. Column 5 references applicable requirements for bottom openings in part 178 of this subchapter. Mass detonate means more than 90 percent of the devices tested in a package explode practically simultaneously. Large Packagings are authorized for the Packing Group III entries of specific proper shipping names when either special provision IB3 or IB8 is assigned to that entry in the 172.101 Table. Each transport unit must be leakproof when used as bulk packaging. B69 Dry sodium cyanide or potassium cyanide may be shipped in the following sift-proof and weather-resistant packagings: metal covered hopper cars, covered motor vehicles, portable tanks, or non-specification bins. will bring you directly to the content. Cargo and portable tanks must have a design pressure of at least 1,207 kPa (175 psig). The rechargeable (and some non-rechargeable) types have gelled alkaline electrolytes (rather than acidic) making it difficult for them to generate hydrogen or oxygen when overcharged and therefore, differentiating them from non-spillable batteries. 155 Fish meal, fish scrap and krill meal may not be transported if the temperature at the time of loading either exceeds 35 C (95 F), or exceeds 5 C (41 F) above the ambient temperature, whichever is higher. subject to the Hazardous Materials Regulations must comply with all applicable requirements of Subpart F [172.500]. Each portable tank constructed of metal must be fitted with a pressure-relief device consisting of a reclosing spring loaded type, a frangible disc or a fusible element. The material may only be loaded with Class 3, Class 8, and Division 4.1 materials in Packing Group II or III. As a (ii) One bottle for every two hours of production, or for every 2,500 bottles produced, must be tested by dropping a bottle filled to 98 percent capacity with water from a height of 1.2 meters (3.9 feet) onto solid concrete directly on the closure. Net weight of contents may not exceed 15 kg (33 pounds). Note 1: Based on maximum lading pressure of 1 psig at top of cargo tank. Use the navigation links in the gray bar above to view the table of contents that this content belongs to. (c) Tables of special provisions. j. 114 Jet perforating guns, charged, oil well, without detonator may be reclassed to Division 1.4 Compatibility Group D (1.4D) if the following conditions are met: a. 347 Effective July 1, 2011, for transportation by aircraft, this entry may only be used if the results of Test series 6(d) of Part I of the UN Manual of Tests and Criteria (IBR, see 171.7 of this subchapter) have demonstrated that any hazardous effects from accidental functioning are confined to within the package. Model rocket motors containing 30 grams or less propellant are classed as Division 1.4S and items containing more than 30 grams of propellant but not more than 62.5 grams of propellant are classed as Division 1.4C. The material is also be subject to operational controls which include not exceeding a temperature of 55C (130F) at the time it is offered or during transportation, not exceeding a transportation time of 24 hours, and drivers transporting spent bleaching earth must be trained in the properties and hazards of the spent bleaching earth. Except for a portable tank containing refrigerated liquefied helium, a portable tank shall have an outage of at least two percent below the inlet of the pressure relief device or pressure control valve, under conditions of incipient opening, with the portable tank in a level attitude. f. The properties of mechanical strength mentioned in this special provision shall be tested using a prototype of a receptacle and/or dispenser filled to nominal capacity, by increasing the temperature until the specified pressures are reached. The means of protection must be approved by the approval agency designated to approve the portable tank in accordance with the procedures in part 107, subpart E, of this subchapter. TP24 The portable tank may be fitted with a device to prevent the build up of excess pressure due to the slow decomposition of the hazardous material being transported. 368 In the case of non-fissile or fissile-excepted uranium hexafluoride, the material must be classified under UN3507 or UN2978. In accordance with Special Provision 8 in 172.102, which is referenced in Column 7 of the Hazardous Materials Table (HMT; 172.101) for the entry "UN3082, Environmentally hazardous substance, liquid, n.o.s.," a hazardous substance that is not a hazardous waste may be shipped under the shipping description "Other regulated substances . When phlegmatized with water and inorganic inert material, the content of urea nitrate must not exceed 75 percent by mass and the mixture should not be capable of being detonated by test 1(a)(i) or test 1(a)(ii) in the UN Manual of Tests and Criteria (IBR, see 171.7 of this subchapter). Liquefied compressed gases are assigned to portable tank instruction T50. 338 Life Saving appliances, self-inflating transported by motor vehicle only between an U.S. Coast Guard approved inflatable life raft servicing facility and a vessel are only subject to the following requirements: a. B30 MC 312, MC 330, MC 331 and DOT 412 cargo tanks and DOT 51 portable tanks must be made of stainless steel, except that steel other than stainless steel may be used in accordance with the provisions of 173.24b(b) of this subchapter. The vacant space (outage) may be charged with a nonflammable nonliquefied compressed gas if the pressure in the cylinder or sphere at 55 C (130 F) does not exceed 125 percent of the marked service pressure. the hierarchy of the document.